SETARAMȍ˂ Calvet Calorimeter |
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Temperature range |
: -196¡É to 300¡É |
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Heating & Cooling rate |
: +/- 0.001 to 2¡ÆC/min |
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µî¿Â»óÅ¿¡¼ ½Ã·áÀÇ ¹ÝÀÀ¿ ÃøÁ¤ |
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Gas-Liquid, Gas-Solid, Liquid-Solid ¹ÝÀÀ |
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½Â¿Â ¹× ³Ã°¢ ½Ã ½Ã·áÀÇ ¹ÝÀÀ¿ ÃøÁ¤ |
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¾×ü, °íü, ÆÄ¿ì´õÀÇ Cp ¹× À¶ÇØ¿ ÃøÁ¤ |
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±ØÀú¿Â»óÅÂ( down to -196¡É)¿¡¼ ½Ã·áÀÇ ÀÀ°í ¹× °áÁ¤È ºÐ¼® |
½Ã·á¸í : Di-tert-butyl peroxide (497.65mg)
±â±â : SETARAM C80 calvet calorimeter
ÀÀ¿ë ºÐ¼®±â¹ý : freeman-carroll method
ÃøÁ¤ Á¶°Ç : from 35 to 200¡É
°á°ú :¿ºÐÇØ ¿£Å»ÇÇ : 1358J/g
È°¼ºÈ ¿¡³ÊÁö : Ea=37.07 kcal/mole
LogK0 : 36.02
½Ã·á¸í : Formol[0.006mol(632mg)] + Butanal[0.002mol(145mg)] in Soda 30%
[0.002mol(267mg)]
±â±â : SETARAM C80 calvet calorimeter
ÃøÁ¤ Á¶°Ç : isothermal 39¡É
°á°ú : Formol ¹× ButanalÀÌ Soda¿ë¸Å¿Í Æø¹ßÀûÀÎ ¹ÝÀÀ ÀÏÀ¸Å´.
¹ÝÀÀÀº ÃÑ 120ºÐ¿¡ °ÉÃÄ ÀϾ.
¹ÝÀÀ¿£Å»ÇÇ´Â 115kJ/mol
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