C 80 & BT 2.15

SETARAMȍ˂ Calvet Calorimeter
Temperature range : -196¡É to 300¡É
Heating & Cooling rate : +/- 0.001 to 2¡ÆC/min
µî¿Â»óÅ¿¡¼­ ½Ã·áÀÇ ¹ÝÀÀ¿­ ÃøÁ¤
Gas-Liquid, Gas-Solid, Liquid-Solid ¹ÝÀÀ
½Â¿Â ¹× ³Ã°¢ ½Ã ½Ã·áÀÇ ¹ÝÀÀ¿­ ÃøÁ¤
¾×ü, °íü, ÆÄ¿ì´õÀÇ Cp ¹× À¶ÇØ¿­ ÃøÁ¤
±ØÀú¿Â»óÅÂ( down to -196¡É)¿¡¼­ ½Ã·áÀÇ ÀÀ°í ¹× °áÁ¤È­ ºÐ¼®


½Ã·á¸í : Di-tert-butyl peroxide (497.65mg)
±â±â : SETARAM C80 calvet calorimeter
ÀÀ¿ë ºÐ¼®±â¹ý : freeman-carroll method
ÃøÁ¤ Á¶°Ç : from 35 to 200¡É
°á°ú :¿­ºÐÇØ ¿£Å»ÇÇ : 1358J/g
È°¼ºÈ­ ¿¡³ÊÁö : Ea=37.07 kcal/mole
LogK0 : 36.02


½Ã·á¸í : Formol[0.006mol(632mg)] + Butanal[0.002mol(145mg)] in Soda 30%
            [0.002mol(267mg)]
±â±â : SETARAM C80 calvet calorimeter
ÃøÁ¤ Á¶°Ç : isothermal 39¡É
°á°ú : Formol ¹× ButanalÀÌ Soda¿ë¸Å¿Í Æø¹ßÀûÀÎ ¹ÝÀÀ ÀÏÀ¸Å´.
         ¹ÝÀÀÀº ÃÑ 120ºÐ¿¡ °ÉÃÄ ÀϾ.
         ¹ÝÀÀ¿£Å»ÇÇ´Â 115kJ/mol