Fig. 2a¸¦ º¸¸é CaSO4ÀÇ È¯¿ø¹ÝÀÀÀÇ ¼Óµµ´Â ¿Âµµ¿¡ µû¶ó ¸Å¿ì ºü¸£°Ô Áõ°¡ÇÏ´Â °ÍÀ» º¼ ¼ö ÀÖ´Ù. Fig. 2bÀÇ DTG °î¼±(TGÀÇ ¹ÌºÐ°î¼±)À» ÅëÇØ È¯¿ø¹ÝÀÀµ¿¾È µÎ °³ÀÇ ¿¬¼ÓÀûÀÎ ¹ÝÀÀÀÌ ¹ß»ýÇÏ´Â °ÍÀ» È®ÀÎÇÒ ¼ö ÀÖ´Ù. ÀÌ·± ȯ¿ø¹ÝÀÀ¿¡ ´ëÇÑ ½Ã°£¿¡ ´ëÇÑ µ¥ÀÌÅ͵éÀº chemical looping combustion¿¡¼­ fuel reactorÀÇ À¯µ¿Ãþ(Fluidized bed)À» ¿¬±¸Çϴµ¥ À¯¿ëÇÏ°Ô »ç¿ëÀÌ µÈ´Ù.

Fig.3À» ÅëÇØ »êÈ­¹ÝÀÀ¿¡ ´ëÇÑ µ¥ÀÌÅ͸¦ º¼¼öÀÖÀ¸¸ç, ½ÇÇèÀÇ Ã¹ ¹ø° ´Ü°è¿¡¼­ CaS°¡ CaSO4·Î ¸Å¿ì ºü¸£°Ô ÀüȯµÇ´Â °ÍÀ» È®ÀÎÇÒ ¼ö ÀÖ´Ù. Àüȯ¼Óµµ´Â ³·Àº ¿ÂµµÀϼö·Ï ´õ ºü¸£°Ô ÁøÇàµÇ´Â °ÍÀ» ¾Ë ¼ö ÀÖ¾úÀ¸¸ç, »ê¼Ò ºÐ¾ÐÀÌ Ä¿Áú¼ö·Ï Áõ´ëµÇ´Â °ÍÀ» È®ÀÎÇÒ ¼ö ÀÖ¾ú´Ù.

Setsys TGA systemÀº ¿©·¯ °¡½º(ºñÈ°¼º°¡½º, ¹ÝÀÀ°¡½º(»êÈ­,ȯ¿ø)µî)µéÀ» »ç¿ëÇÏ¿© ½ÇÇèÇϴµ¥ À¯¿ëÇÏ°Ô »ç¿ëµÇ´Â ÀåÁ¡ÀÌ ÀÖ´Ù. ¶ÇÇÑ air reactor°¡ »ç¿ëµÇ´Â ÀûÇտµµÀÎ 1050~1150¡É, ±×¸®°í fuel reactor°¡ »ç¿ëµÇ´Â ÀûÇտµµÀÎ 900~950¡É»çÀÌÀÇ ¿Âµµ¸¦ ÃÖÀûÈ­ÇÏ¿© Á¤È®ÇÑ Å×½ºÆ®°¡ °¡´ÉÇÏ´Ù.

Setsys TGA systemÀº ¶ÇÇÑ ´Ù¾çÇÑ °¡½º(humid gasÆ÷ÇÔ)¿¡ ´ëÇÑ NiO¿Í Fe2O3ÀÇ ¸Åü¼øȯ°¡½º ¿¬¼Ò½ÇÇè(Chemical looping combustion, CLC)¿¡µµ ÀûÇÕÇÏ´Ù. ¶ÇÇÑ ´ëĪÇü ÀüÀÚÀú¿ï ¹æ½ÄÀÇ TAG systemÀ» ÀÌ¿ëÇÏ¿© Mn-Fe(¸Á°£-ö) È¥ÇÕ »êÈ­¹°¿¡ ´ëÇÑ »êÈ­, ȯ¿ø ¿¬¼Ó ¼øȯ¹ÝÀÀ¿¡ ´ëÇÑ ÃøÁ¤µµ °¡´ÉÇÏ´Ù.

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2_ Sung Real Son and Sang Done Kim, Chemical-looping combustion with NiO and Fe203 in a thermobalance and circulating fluidized bed reactor with double loops. Ind. Eng. Chem. Res., 45, 2689-2696 (2006)

3_ Arnold Lambert, Celine Delquie, I. Clemencon, Elodid Comte, Veronique Lefebvre, J.Rousseau, B. Durand, Synthesis and characterization of bimetallic Fe/Mn oxides for chemical looping combustion, Energy Procedia 1 (2009) 375-381